[Au]/[Pd] Multicatalytic Processes: Direct One‐Pot Access to Benzo[ c ]chromenes and Benzo[ b ]furans - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2014

[Au]/[Pd] Multicatalytic Processes: Direct One‐Pot Access to Benzo[ c ]chromenes and Benzo[ b ]furans

Yoshihiro Oonishi
  • Fonction : Auteur
Adrián Gómez-Suárez
  • Fonction : Auteur
Yusuke Makida
  • Fonction : Auteur
Alexandra Slawin
  • Fonction : Auteur
Steven Nolan
  • Fonction : Auteur

Résumé

Abstract A new synthetic protocol that combines the advantages offered by eco‐friendly solvent‐free reactions and sequential transformations is reported. This strategy offers straightforward access to benzo[ c ]chromenes and benzo[ b ]furans from commercially available starting materials. This two‐step, one‐pot strategy consists of an Au‐catalyzed hydrophenoxylation process followed by Pd‐catalyzed CH activation or Mizoroki–Heck reactions. The selectivity of the process towards CH activation or Mizoroki–Heck reaction can be easily tuned.

Domaines

Catalyse

Dates et versions

hal-04599364 , version 1 (03-06-2024)

Identifiants

Citer

Yoshihiro Oonishi, Adrián Gómez-Suárez, Anthony Martin, Yusuke Makida, Alexandra Slawin, et al.. [Au]/[Pd] Multicatalytic Processes: Direct One‐Pot Access to Benzo[ c ]chromenes and Benzo[ b ]furans. Chemistry - A European Journal, 2014, 20 (42), pp.13507-13510. ⟨10.1002/chem.201404630⟩. ⟨hal-04599364⟩
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