We use analytical and $N$-body methods to study the capture of field stars by gravitating substructures moving across a galactic environment. We find that the majority of captured stars move on temporarily-bound orbits that escape from the substructure potential after a few orbital revolutions. In numerical experiments where a substructure model is immersed in a galaxy on a circular orbit, we also find particles that remain bound to the substructure potential for indefinitely-long times. This population is absent from substructure models initially placed outside the galaxy on an eccentric orbit. We show that gravitational capture is most efficient in dwarf spheroidal galaxies (dSphs) on account of their low velocity dispersions and high stellar phase-space densities. In these galaxies `dark' sub-subhaloes which do not experience in-situ star formation may capture field stars and become visible as stellar overdensities with unusual properties: (i) they would have a large size for their luminosity, (ii) contain stellar populations indistinguishable from the host galaxy, and (iii) exhibit dark matter (DM)-dominated mass-to-light ratios. We discuss the nature of several `anomalous' stellar systems reported as star clusters in the Fornax and Eridanus II dSphs which exhibit some of these characteristics. A large population of DM sub-subhaloes with a mass function $d N/d M_\bullet\sim M_\bullet^{-\alpha}$ generates stellar substructures with a luminosity function, $d N/d M_\star\sim M_\star^{-\beta}$, where $\beta=(2\alpha+1)/3=1.6$ for $\alpha=1.9$. Detecting and characterizing these objects in dSphs would provide unprecedented constraints on the particle mass and cross section of a large range of DM particle candidates.