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Article Dans Une Revue Molecules Année : 2014

Photochemistry and Radical Chemistry under Low Intensity Visible Light Sources: Application to Photopolymerization Reactions

Celine Dietlin
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Bernadette Graff
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Jean-Pierre Fouassier
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Résumé

The search for radical initiators able to work under soft conditions is a great challenge, driven by the fact that the use of safe and cheap light sources is very attractive. In the present paper, a review of some recently reported photoinitiating systems for polymerization under soft conditions is provided. Different approaches based on multi-component systems (e.g., photoredox catalysis) or light harvesting photoinitiators are described and discussed. The chemical mechanisms associated with the production of free radicals usable as initiating species or mediators of cations are reported.
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hal-04559926 , version 1 (25-04-2024)

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Jacques Lalevée, Fabrice Morlet-Savary, Celine Dietlin, Bernadette Graff, Jean-Pierre Fouassier. Photochemistry and Radical Chemistry under Low Intensity Visible Light Sources: Application to Photopolymerization Reactions. Molecules, 2014, 19 (9), pp.15026-15041. ⟨10.3390/molecules190915026⟩. ⟨hal-04559926⟩
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