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Article Dans Une Revue European Polymer Journal Année : 2024

Polymers with one free gallic acid per monomer unit. Controlled synthesis and intrinsic antioxidant/antibacterial properties

Résumé

The development of bio-based thermoplastics is rapidly growing due to the depletion of fossil fuel reserves but also in the hope of obtaining polymers with original properties. Herein, we report the controlled synthesis of original homopolymers derived from gallic acid, one of the well-known natural polyphenols that exhibits various health-promoting effects. More precisely, acrylate, methacrylate and acrylamide monomers based on a protected gallic acid are firstly obtained by a rethought multistep scheme. Then, a controlled photo-mediated RAFT (Reversible Addition Fragmentation chain Transfer) polymerization was carried out before a final deprotection. By this way, original polymers bearing a free gallic acid as a lateral substituent on each monomer unit are described. The intrinsic antibacterial and antioxidant properties of these polymers are highlighted and compared with those of gallic acid.
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mardi 8 octobre 2024
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Dates et versions

hal-04537005 , version 1 (08-04-2024)

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Ali Khalil, Carmen Moya Lopez, Francisco Carlos Pérez-Martínez, Christine Gerardin-Charbonnier, Khalid Ferji, et al.. Polymers with one free gallic acid per monomer unit. Controlled synthesis and intrinsic antioxidant/antibacterial properties. European Polymer Journal, 2024, pp.113022. ⟨10.1016/j.eurpolymj.2024.113022⟩. ⟨hal-04537005⟩
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