Bis(µ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth, the first example of a Bi(III) thiocarbamate compound
Résumé
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI3 was reacted with two equivalents of MeOC(=S)N(H)Ph L in MeCN solution to afford the dinuclear title compound complexes [{I2Bi(µ2-I)2BiI2} {κ1-MeOC(=S)N(H)Ph}4] C1.
Compound C1 was characterized by IR, UV and NMR spectroscopy, the formation of a dinuclear framework is ascertained by a single-crystal X-ray diffraction study performed at 100 K.