Bis(µ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth, the first example of a Bi(III) thiocarbamate compound - Archive ouverte HAL Accéder directement au contenu
Poster De Conférence Année : 2023

Bis(µ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth, the first example of a Bi(III) thiocarbamate compound

Résumé

In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI3 was reacted with two equivalents of MeOC(=S)N(H)Ph L in MeCN solution to afford the dinuclear title compound complexes [{I2Bi(µ2-I)2BiI2} {κ1-MeOC(=S)N(H)Ph}4] C1. Compound C1 was characterized by IR, UV and NMR spectroscopy, the formation of a dinuclear framework is ascertained by a single-crystal X-ray diffraction study performed at 100 K.

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Chimie
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Dates et versions

hal-04506111 , version 1 (15-03-2024)

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  • HAL Id : hal-04506111 , version 1

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Wafa Arar, Abderrahim Khatyr, Michael Knorr, Carsten Strohmann, Annika Schmid. Bis(µ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth, the first example of a Bi(III) thiocarbamate compound. Organic Chemistry Conference Science and Engineering of Polymeric Materials - OCC & SEPM 2023, Hammamet, Tunisie, May 2023, Hammamet (TUN), Tunisia. . ⟨hal-04506111⟩
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