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Article Dans Une Revue Chemical Communications Année : 2009

Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand

Résumé

A new polymeric approach, based on cyanocarbanion ligands, for the design of spin crossover (SCO) compounds led us to the compound [Fe(abpt)2(tcpd)] (1) (tcpd2− = (C[C(CN)2]3)2−, abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) which has been characterised as the first SCO molecular chain involving a cyanocarbanion as bridging ligand.

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Matériaux
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Dates et versions

hal-04493032 , version 1 (06-03-2024)

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Gaelle Dupouy, Mathieu Marchivie, Smail Triki, Jean Sala-Pala, Carlos Gómez-García, et al.. Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand. Chemical Communications, 2009, 23, pp.3404. ⟨10.1039/b902339a⟩. ⟨hal-04493032⟩
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