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Pré-Publication, Document De Travail Année : 2023

Breaking 1.7V open circuit voltage in large area transparent perovskite solar cells using bulk and interfaces passivation.

Fabio Matteocci
Francesco Di Giacomo
Farshad Jafarzadeh
Luigi Angelo Castriotta
Mathieu Frégnaux

Résumé

Abstract Efficient semi-transparent solar cells can trigger the adoption of building integrated photovoltaics. Halide perovskites are particularly suitable in this respect owing to their tunable bandgap. Main drawbacks in the development of transparent perovskite solar cells are the high Voc deficit and the difficulties in depositing thin films over large area substrates, given the low solubility of bromide and chloride precursors. In this work, we develop a 2D and passivation strategies for the high band-gap Br perovskite able to reduce charge recombination and consequently improving the open-circuit voltage. We demonstrate 1cm 2 perovskite solar cells with Voc up to 1.73 V (1.83 eV QFLS) and a PCE of 8.2%. The AVT exceeds 70% by means of a bifacial light management and a record light utilization efficiency of 5.72 is achieved, setting a new standard for transparent photovoltaics. Moreover, we show the high ceiling of our technology towards IoT application due to a bifaciality factor of 87% along with 17% PCE under indoor lighting. Finally, the up-scaling has been demonstrated fabricating 20cm 2 -active area modules with PCE of 7.3% and Voc per cell up to 1.65V.
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hal-04427429 , version 1 (30-01-2024)

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Paternité - Pas d'utilisation commerciale - Partage selon les Conditions Initiales

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Fabio Matteocci, Diego Di Girolamo, Guillame Vidon, Jessica Barichello, Francesco Di Giacomo, et al.. Breaking 1.7V open circuit voltage in large area transparent perovskite solar cells using bulk and interfaces passivation.. 2024. ⟨hal-04427429⟩
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