Article Dans Une Revue Chemistry - A European Journal Année : 2017

Trifluoromethyl‐ and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds

Thierry Billard
Anis Tlili

Résumé

Abstract The successful perfluoroalkylselenolation of alkynyl copper(I) compounds is described herein. The reaction occurs under oxidant free conditions at room temperature. This convenient one‐pot procedure is based on the in situ generation of trifluoromethylselenyl chlorides. The developed system shows high functional group tolerance and also promotes the employment of fluoroalkyl derivatives.

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Dates et versions

hal-04409412 , version 1 (22-01-2024)

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Clément Ghiazza, Thierry Billard, Anis Tlili. Trifluoromethyl‐ and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds. Chemistry - A European Journal, 2017, 23 (42), pp.10013-10016. ⟨10.1002/chem.201702028⟩. ⟨hal-04409412⟩
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