Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds
Résumé
Hypervalent iodine compounds are described with perfluoroalkyl chains and S ‐perfluoromethyl sulfoximines as ligands of the halogen. The influence of these groups on the stability of the cyclic structure is studied. The crucial role of the trifluoromethyl chain is clearly highlighted as an efficient ligand for the hypervalency. The structure and the reactivity of the new skeletons are discussed in detail.
Domaines
Chimie organique
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Eur J Org Chem - 2023 - Duhail - Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents The Crucial Role of.pdf (5.12 Mo)
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