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Article Dans Une Revue Angewandte Chemie International Edition Année : 2023

MOFs with Open Metal(III) Sites for the Environmental Capture of Polar Volatile Organic Compounds

Marco Daturi
Christian Serre

Résumé

Metal-Organic Frameworks (MOF) with open metal sites (OMS) interact strongly with a range of polar gases/vapors. However, under ambient conditions, their selective adsorption is generally impaired due to a high OMS affinity to water. This led previously to the privilege selection of hydrophobic MOFs for the selective capture/detection of volatile organic compounds (VOCs). Herein, we show that this paradigm is challenged by metal(III) polycarboxylates MOFs, bearing a high concentration of OMS, as MIL-100(Fe), enabling the selective capture of polar VOCs even in the presence of water. With experimental and computational tools, including singlecomponent gravimetric and dynamic mixture adsorption measurements, in situ infrared (IR) spectroscopy and Density Functional Theory calculations we reveal that this adsorption mechanism involves a direct coordination of the VOC on the OMS, associated with an interaction energy that exceeds that of water. Hence, MOFs with OMS are demonstrated to be of interest for air purification purposes.
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Dates et versions

hal-04306158 , version 1 (24-11-2023)

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Maria Inês Severino, Abeer Al Mohtar, Carla Vieira Soares, Cátia Freitas, Nicolas Sadovnik, et al.. MOFs with Open Metal(III) Sites for the Environmental Capture of Polar Volatile Organic Compounds. Angewandte Chemie International Edition, 2023, 62 (6), pp.e202211583. ⟨10.1002/anie.202211583⟩. ⟨hal-04306158⟩
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