Insight into Interfacial Charge Transfer during Photocatalytic H 2 Evolution through Fe, Ni, Cu and Au Embedded in a Mesoporous TiO2@SiO2 Core‐shell - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue ChemCatChem Année : 2022

Insight into Interfacial Charge Transfer during Photocatalytic H 2 Evolution through Fe, Ni, Cu and Au Embedded in a Mesoporous TiO2@SiO2 Core‐shell

Résumé

Abstract The efficiency of charge transfer at the interface of transition metals loaded on TiO 2 as well as the active reduction site undoubtedly define the kinetics of H 2 production. Here, we report the interfacial charge process of various transition metals (Fe, Ni, Cu, and Au) embedded in mesoporous core‐shell nanostructures, which provides further insight into the photocatalytic H 2 evolution. Au was found to be the most active cocatalyst for the H 2 evolution. Au nanoparticles (NPs) collect electrons and become a very efficient reduction site, promoting both charge separation and H 2 evolution. The scavenging capacity of Au was found to be the highest compared to other NPs. Cu(I), which is as active as Au, but at a higher loading, also shows an ability for electron scavenging and acts as an active site under UV excitation, or rather injects electrons into the TiO 2 conduction band under visible excitation. Ni(II) NPs were found to be involved in charge‐carrier separation through hole collection and their contribution to hydrogen evolution is expected to be limited to visible absorption and electron injection. The same behavior occurs with Fe(III), however, it is less efficient for H 2 generation due to the weak charge‐carrier lifetime. We show that only Cu(I) could compete with noble metals such as Au, presenting electron‐scavenging behavior. Understanding the charge‐carrier dynamics will help design a very efficient system for photocatalytic H 2 generation system.

Domaines

Chimie

Dates et versions

hal-04273281 , version 1 (07-11-2023)

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Citer

Qian Xu, Marija Knezevic, Abdelghani Laachachi, Sylvain Franger, Christophe Colbeau-Justin, et al.. Insight into Interfacial Charge Transfer during Photocatalytic H 2 Evolution through Fe, Ni, Cu and Au Embedded in a Mesoporous TiO2@SiO2 Core‐shell. ChemCatChem, 2022, 14 (12), ⟨10.1002/cctc.202200102⟩. ⟨hal-04273281⟩
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