Regio‐ and Stereoselective Iron‐Catalyzed Oxyazidation of Enamides Using a Hypervalent Iodine Reagent - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2017

Regio‐ and Stereoselective Iron‐Catalyzed Oxyazidation of Enamides Using a Hypervalent Iodine Reagent

Résumé

Abstract A novel regio‐ and diastereoselective iron‐catalyzed intermolecular oxyazidation of enamides using various azidobenziodoxolone (ABX) derivatives is presented. A variety of α‐N 3 amino derivatives and of α‐N 3 piperidines were synthesized in good yields and under mild reaction conditions. The reaction involves a radical process using cheap FeCl 2 as the initiator.

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Chimie
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Dates et versions

hal-04270183 , version 1 (03-11-2023)

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Citer

Sylvain Bertho, Romain Rey-Rodriguez, Cyril Colas, Pascal Retailleau, Isabelle Gillaizeau. Regio‐ and Stereoselective Iron‐Catalyzed Oxyazidation of Enamides Using a Hypervalent Iodine Reagent. Chemistry - A European Journal, 2017, 23 (70), pp.17674-17677. ⟨10.1002/chem.201704499⟩. ⟨hal-04270183⟩
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