Dual-Responsive and Reusable Optical Sensors Based on 2,3-Diaminoquinoxalines for Acidity Measurements in Low-pH Aqueous Solutions - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Sensors Année : 2023

Dual-Responsive and Reusable Optical Sensors Based on 2,3-Diaminoquinoxalines for Acidity Measurements in Low-pH Aqueous Solutions

Résumé

This work is focused on the age-old challenge of developing optical sensors for acidity measurements in low-pH aqueous solutions (pH < 5). We prepared halochromic (3-aminopropyl)amino-substituted quinoxalines QC1 and QC8 possessing different hydrophilic–lipophilic balance (HLB) and investigated them as molecular components of pH sensors. Embedding the hydrophilic quinoxaline QC1 into the agarose matrix by sol-gel process allows for fabrication of pH responsive polymers and paper test strips. The emissive films thus obtained can be used for a semi-quantitative dual-color visualization of pH in aqueous solution. Being exposed to acidic solutions with pH in the range of 1–5, they rapidly give different color changes when the analysis is performed in daylight or under irradiation at 365 nm. Compared with classical non-emissive pH indicators, these dual-responsive pH sensors allow for an increase in the accuracy of pH measurements, particularly in complex environmental samples. pH indicators for quantitative analysis can be prepared by the immobilization of amphiphilic quinoxaline QC8 using Langmuir–Blodgett (LB) and Langmuir–Schäfer (LS) techniques. Compound QC8 possessing two long alkyl chains (n-C8H17) forms stable Langmuir monolayers at the air–water interface, and these monolayers can be successfully transferred onto hydrophilic quartz and hydrophobic polyvinylchlorid (PVC) substrates using LB and LS techniques, respectively. The 30-layer films thus obtained are emissive, reveal excellent stability, and can be used as dual-responsive pH indicators for quantitative measurements in real-world samples with pH in the range of 1–3. The films can be regenerated by immersing them in basic aqueous solution (pH = 11) and can be reused at least five times.
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Dates et versions

hal-04264047 , version 1 (29-10-2023)

Identifiants

Citer

Elizaveta Ermakova, Anastasia Bol’shakova, Alla G. Bessmertnykh-Lemeune. Dual-Responsive and Reusable Optical Sensors Based on 2,3-Diaminoquinoxalines for Acidity Measurements in Low-pH Aqueous Solutions. Sensors, 2023, 23 (6), pp.2978. ⟨10.3390/s23062978⟩. ⟨hal-04264047⟩
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