Kinetic delay in cooperative supramolecular polymerization by redefining the trade‐off relationship between H‐bonds and Van der Waals / π‐ π stacking interactions. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2023

Kinetic delay in cooperative supramolecular polymerization by redefining the trade‐off relationship between H‐bonds and Van der Waals / π‐ π stacking interactions.

Résumé

We here present how rebalancing the interplay between H‐bonds and dispersive forces (Van der Waals / π‐ π stacking) may induce or not generation of kinetic metastable states. In particular, we show that extending aromatic content favouring interchain VdW interactions causes a delay into cooperative supramolecular polymerization new family toluene bis‐amide derivatives by trapping inactive state.
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Dates et versions

hal-04262689 , version 1 (27-10-2023)

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William T. Gallonde, Corentin Poidevin, Felix Houard, Elsa Caytan, Vincent Dorcet, et al.. Kinetic delay in cooperative supramolecular polymerization by redefining the trade‐off relationship between H‐bonds and Van der Waals / π‐ π stacking interactions.. Angewandte Chemie International Edition, In press, ⟨10.1002/anie.202313696⟩. ⟨hal-04262689⟩
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