Journal Articles Chem Catalysis Year : 2023

Tuning catalyst performance in asymmetric carbene transfer toward CF3-cyclopropenes

Abstract

In this issue of Chem Catalysis, Zhang, Ma, Marek, et al. report a highly enantioselective carbene-transfer reaction of 2,2,2-trifluorodiazoethane (CF3CHN2) and challenging disubstituted alkynes. Key to the success of this approach is the fine-tuning of chiral dirhodium(II) carboxylate paddlewheel complexes featuring a molecule of dioxane as achiral axial ligand.

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hal-04234771 , version 1 (10-10-2023)

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Nicolas Marie, Dominique Cahard. Tuning catalyst performance in asymmetric carbene transfer toward CF3-cyclopropenes. Chem Catalysis, 2023, 3 (6), pp.100665. ⟨10.1016/j.checat.2023.100665⟩. ⟨hal-04234771⟩
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