High-order adaptive multi-domain time integration scheme for microscale lithium-ion batteries simulations
Résumé
We investigate the modeling and simulation of ionic transport and charge conservation in
lithium-ion batteries (LIBs) at the microscale. It is a multiphysics problem that involves a wide range of
time scales. The associated computational challenges motivate the investigation of numerical techniques
that can decouple the time integration of the governing equations in the liquid electrolyte and the solid
phase (active materials and current collectors). First, it is shown that semi-discretization in space of the
non-dimensionalized governing equations leads to a system of index-1 semi-explicit differential algebraic
equations (DAEs). Then, a new generation of strategies for multi-domain integration is presented,
enabling high-order adaptive coupling of both domains in time, with efficient and potentially different
domain integrators. They reach a high level of flexibility for real applications, beyond the limitations of
multirate methods. A simple 1D LIB half-cell code is implemented as a demonstrator of the new strategy
for the simulation of different modes of cell operation. The integration of the decoupled subsystems is
performed with high-order accurate implicit nonlinear solvers. The accuracy of the space discretization
is assessed by comparing the numerical results to the analytical solutions. Then, temporal convergence
studies demonstrate the accuracy of the new multi-domain coupling approach. Finally, the accuracy and
computational efficiency of the adaptive coupling strategy are discussed in the light of the conditioning
of the decoupled subproblems compared to the one of the fully-coupled problem. This new approach
will constitute a key ingredient for the high-fidelity 3D LIB simulations based on actual electrode
microstructures.
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