Photoinduced electron transfer between a noble-metal-free [Mo(6)I(8)Cl(6)](2-) cluster and polyoxometalates
Résumé
Evidence for photoinduced intermolecular electron transfer from the excited state of the [Mo(6)I(8)Cl(6)](2-) electron-rich cluster to polyoxometalates (POMs) is reported. We demonstrate that the global charge density of POMs affects the efficiency of electron transfer. This work paves the way for the rational design of photocatalytic systems using cluster-based complexes as robust noble-metal-free photosensitizers.
Domaines
Chimie
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Fatima et al - 2023 - Photoinduced electron transfer between a noble-metal-free _Electron_transfer_ClusPOM_ChemCommun_Manuscript_hal.pdf (622.92 Ko)
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d3cc03334a1.pdf (1.55 Mo)
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