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Article Dans Une Revue Australian Journal of Chemistry Année : 2003

Unimolecular Rearrangements of Transient Carboxy Radicals and Cations

Résumé

Charge reversal (CR) and neutralization–reionization (NR) mass spectra of aliphatic carboxylate ions RCOO– provide insight into the behaviour of the transient neutral carboxy radicals RCOO• as well as the short-lived RCOO+ cations. For the neutral radicals, a novel hydrogen rearrangement is proposed, which might explain the sometimes only modest yields in the Hunsdiecker reaction of carboxylic acids in the condensed phase.
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Dates et versions

hal-04163703 , version 1 (17-07-2023)

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Detlef Schröder, Héloïse Soldi-Lose, Helmut Schwarz. Unimolecular Rearrangements of Transient Carboxy Radicals and Cations. Australian Journal of Chemistry, 2003, 56 (5), pp.443. ⟨10.1071/CH02265⟩. ⟨hal-04163703⟩
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