Functionalization of Carbon Surfaces Using the Copper-Catalyzed Diels–Alder Reaction - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemistry of Materials Année : 2023

Functionalization of Carbon Surfaces Using the Copper-Catalyzed Diels–Alder Reaction

Wolfgang Knoll
Charles Cougnon
  • Fonction : Auteur
Essraa Ahmed
Paulius Pobedinskas
Ken Haenen

Résumé

We propose here a new method to functionalize carbon materials via a catalyzed Diels–Alder reaction. In a Diels–Alder reaction, carbon materials can be used as a diene or a dienophile. Here, carbon materials are used as dienes and alkyne-terminated derivatives as dienophiles. Different carbon materials, i.e., glassy carbon, carbon powder (carbon black), pyrolytic graphite carbon materials, and graphene, were functionalized by alkyne ferrocene derivatives or perfluoro-tagged alkyne molecules and characterized by electrochemical means, atomic force microscopy, and X-ray photoelectron spectroscopy experiments. This method allows for the rapid functionalization of carbon materials in mild conditions with high surface coverage.

Domaines

Matériaux Catalyse
Fichier principal
Vignette du fichier
manuscript_diels-alder_revised-3.pdf (1.24 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-04161169 , version 1 (13-07-2023)

Identifiants

Citer

Denis Ari, Jean-Francois Bergamini, Teresa Rodrigues, Wolfgang Knoll, Charles Cougnon, et al.. Functionalization of Carbon Surfaces Using the Copper-Catalyzed Diels–Alder Reaction. Chemistry of Materials, 2023, 35 (13), pp.4935-4944. ⟨10.1021/acs.chemmater.3c00055⟩. ⟨hal-04161169⟩
34 Consultations
4 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More