Quantum Dynamics of the 17O + 32O2 Collision Process - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Physical Chemistry A Année : 2016

Quantum Dynamics of the 17O + 32O2 Collision Process

Résumé

We report full quantum integral and differential cross sections and rate constants for the 17O + 32O2 reactive process. This constitutes the first quantum scattering study of the 17O16O16O system. We emphasize the comparison with the 18O + 32O2 collision in close connection to the mass-independent fractionation (hereafter referred to as MIF) puzzle for ozone in atmospheric chemistry. We find similar general trends in the cross sections and rate constants for both rare isotopes, but we note some singular behaviors peculiar to the use of 17O isotope, particularly at the lowest collision energies.
Fichier non déposé

Dates et versions

hal-04159170 , version 1 (11-07-2023)

Identifiants

Citer

Grégoire Guillon, Pascal Honvault. Quantum Dynamics of the 17O + 32O2 Collision Process. Journal of Physical Chemistry A, 2016, 120 (42), pp.8254-8258. ⟨10.1021/acs.jpca.6b07547⟩. ⟨hal-04159170⟩
4 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Mastodon Facebook X LinkedIn More