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Article Dans Une Revue Journal of The Electrochemical Society Année : 2021

Corrosion Products Electrochemical Behaviour into Molten LiF-NaF: Investigation of Cr(II) System

Résumé

In this work, a detailed electrochemical study of the molten LiF-NaF-CrF 2 system is provided on Ag electrode in the 750 °C–900 °C temperature range. The first part was dedicated to the electrochemical study, by cyclic and square wave voltammetries, allowing the determination of thermodynamic and physico-chemical data such as CrF 2 /Cr standard potential, diffusion coefficient, activity coefficient, transfer energy and nucleation overvoltage. The influence of Li 2 O addition on the electrochemical reduction pathway of dissolved CrF 2 on a silver electrode was investigated. The results showed that an increase of Li 2 O activity in the solution causes CrF 2 disproportionation into solid chromium oxide and metallic Cr.
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Dates et versions

hal-04142900 , version 1 (05-07-2023)

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Laurent Massot, Mathieu Gibilaro, D. Quaranta, Pierre Chamelot. Corrosion Products Electrochemical Behaviour into Molten LiF-NaF: Investigation of Cr(II) System. Journal of The Electrochemical Society, 2021, 168 (2), pp.026510. ⟨10.1149/1945-7111/abe088⟩. ⟨hal-04142900⟩
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