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Article Dans Une Revue Journal of Molecular Catalysis A: Chemical Année : 2002

Efficiency of a tetraphosphine ligand in palladium catalysed allylic amination

Résumé

A new tetraphosphine, the cis,cis,cis-1,2,3,4-tetrakis (diphenylphosphinomethyl)cyclopentane (Tedicyp), in combination with [Pd(C 3 H 5)Cl] 2 affords a very efficient catalyst for allylic amination. A turnover number of 980 000 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst. This complex is very stable and the reactions can be performed in water without loss of activity.

Domaines

Chimie
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Dates et versions

hal-04056563 , version 1 (02-05-2023)

Identifiants

  • HAL Id : hal-04056563 , version 1

Citer

D. Laurenti, Maurice Santelli, Henri Doucet, Marie Feuerstein. Efficiency of a tetraphosphine ligand in palladium catalysed allylic amination. Journal of Molecular Catalysis A: Chemical, 2002, 182-183, pp.471-480. ⟨hal-04056563⟩
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