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Article Dans Une Revue New Journal of Chemistry Année : 2021

Azido-perylenediimide: a versatile building block for CuAAC reactions and an alternative precursor for N-annulation

Antoine Goujon
Lou Rocard
Piétrick Hudhomme

Résumé

Azido-perylenediimide (N3-PDI) was isolated as a stable solid, which readily converts into N-annulated PDI in solution only when exposed to visible light. N3-PDI was also engaged in CuAAC reactions with alkynes to provide multi-PDI chromophore architectures in excellent yields. This new, easily accessible and highly reactive building block completes the PDI chemistry toolbox for the design of n-type semiconductors and new dyes.

Domaines

Chimie
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Dates et versions

hal-03979981 , version 1 (09-02-2023)

Identifiants

Citer

Antoine Goujon, Lou Rocard, Heorhii Melnychenko, Piétrick Hudhomme. Azido-perylenediimide: a versatile building block for CuAAC reactions and an alternative precursor for N-annulation. New Journal of Chemistry, 2021, 45 (36), pp.16426-16429. ⟨10.1039/D1NJ02130C⟩. ⟨hal-03979981⟩
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