An air-stable radical with a redox-chameleonic amide
Résumé
An air-stable (amino)(amido)radical was synthesized by reacting a cyclic (alkyl)(amino)carbene with carbazoyl chloride, followed by one-electron reduction. We show that an adjacent radical center weakens the amide bond. It enables the amino group to act as a strong acceptor under steric contraint, thus enhancing the stabilizing-capto-dative effect.
Domaines
Chimie organique| Origine | Publication financée par une institution |
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