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Communication Dans Un Congrès Année : 2023

Effects of a non-ionic surfactant admixture on the rheology of dense silica suspensions

Antoine Aubel
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Xavier Chateau
Julie Goyon
Anaël Lemaître

Résumé

Chemical additives are widely used to tune the behavior of dense colloidal suspensions encountered in various industrial fields such as civil engineering, ceramics or cosmetics. Nevertheless, the mechanism by which admixtures modify inter-particle interactions, and thus the overall rheology, remains obscure. As a result, optimization processes rely essentially on a trial and error strategy. Understanding the link between inter-particle contacts and the overall rheology requires to work with model systems, especially when chemicals are added. We therefore prepared dense suspensions with well-controlled properties by dispersing silica beads into an aqueous salt solution mixed with a non-ionic surfactant. We experimentally investigated suspension properties from the contact scale to the overall rheology by combining rheometry, total organic carbon, zeta potential, confocal microscopy and optical tweezers experiments. Our results highlight that the adsorption of surfactant onto silica beads strongly modifies both the contact properties and the microstructure of the suspension, leading to non-monotonic variations in yield stress and elastic shear modulus as a function of the amount of added surfactant. We propose micro-macro scaling relationships to predict the yield stress and elastic shear modulus of the suspension from the contact properties probed with optical tweezers, as depicted in Fig.1.

Domaines

Matériaux
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Dates et versions

hal-03909107 , version 1 (15-02-2023)

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Paternité

Identifiants

  • HAL Id : hal-03909107 , version 1

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Antoine Aubel, Xavier Chateau, Julie Goyon, Anaël Lemaître. Effects of a non-ionic surfactant admixture on the rheology of dense silica suspensions. XIXth International Congress on Rheology (ICR 2023), Jul 2023, Athènes, Greece. 1 p. ⟨hal-03909107⟩
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