Cobalt Bromide-Catalyzed Negishi-Type Cross-Coupling of Amides
Résumé
In this manuscript, a novel Negishi-type cross-coupling of amides was described employing only cobalt bromide salt as catalyst. This original reaction is highly tolerant toward various glutarimide amides as well as organozinc coupling partners. These conditions also allow to perform the cross-coupling reaction in an eco-compatible solvent such as ethyl acetate on a large scale.
Domaines
Chimie
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Article_Negishi_Alkylzinciques_Major corrections_15032022 (1).pdf (583.37 Ko)
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