Theoretical, Semiempirical, and Experimental Solvatochromic Comparison Methods for the Construction of the α 1 Scale of Hydrogen-Bond Donation of Solvents
Résumé
The misused Kamlet-Taft solvatochromic comparison method (SCM) must be replaced by theoretical (PCM-TD-DFT calculations) or semi-empirical (Mc Rae equation) or experimental (comparison of two betaine dyes) SCMs.
Domaines
Chimie
Origine : Fichiers produits par l'(les) auteur(s)