Understanding the Catalytic Deactivation upon Hydrothermal Aging at 850 °C of WO3/Fe-Cu-ZSM-5 Catalyst for Selective Catalytic Reduction of NO by NH3 - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Inorganics Année : 2022

Understanding the Catalytic Deactivation upon Hydrothermal Aging at 850 °C of WO3/Fe-Cu-ZSM-5 Catalyst for Selective Catalytic Reduction of NO by NH3

Résumé

A WO3/Fe-Cu-ZSM-5 catalyst was prepared using the solid state ion exchange method (SSIE) and its performance for the Selective Catalytic Reduction of NO with NH3 (NH3-SCR of NO) was investigated. The study shows that the tungsten addition can slightly improve the high temperature catalytic activity of Fe-Cu-ZSM-5. The influence of hydrothermal aging at 850 °C for 5 h on the structural and textural properties of WO3/Fe-Cu-ZSM-5 was also studied in this paper. The XRD and FE-SEM measurements did not indicate a breakdown of the zeolite structure upon steam treatment for both aged catalysts. The aged W-base catalyst demonstrates a lower deactivation and better catalytic activity for NO reduction than the bimetallic catalyst after hydrothermal aging despite the lower acidic properties as shown by FTIR-Pyr spectroscopy owing to the presence of tungsten oxide crystallites. The "severe" stage of aging occurring in the absence of W led to the formation of copper oxide agglomerates detected using STEM and H2-TPR techniques being responsible for the deterioration of SCR activity of the aged Fe-Cu-ZSM-5.

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Catalyse
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hal-03831696 , version 1 (27-10-2022)

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Houda Jouini, Alessandra de Marcos-Galán, Imène Mejri, Rahma Bensouilah, Mourad Mhamdi, et al.. Understanding the Catalytic Deactivation upon Hydrothermal Aging at 850 °C of WO3/Fe-Cu-ZSM-5 Catalyst for Selective Catalytic Reduction of NO by NH3. Inorganics, 2022, 10 (11), pp.180. ⟨10.3390/inorganics10110180⟩. ⟨hal-03831696⟩
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