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Journal Articles Journal of Organometallic Chemistry Year : 2022

Late stage modifications of phosphine oxide ligands by iron‐catalyzed hydrogen borrowing reactions

Abstract

α-Alkylation reaction involving methyldiarylphosphine oxides and (hetero)arylmethanols as the electrophilic partners can be performed using iron based catalyst under hydrogen borrowing conditions. Various (hetero)arylmethanols can be used leading to the corresponding alkyldiarylphosphine oxides with moderate to good yields. © 2022
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hal-03798833 , version 1 (05-10-2022)

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J. Wu, S.N. Narayanasamy, C. Darcel. Late stage modifications of phosphine oxide ligands by iron‐catalyzed hydrogen borrowing reactions. Journal of Organometallic Chemistry, 2022, 979, pp.122510. ⟨10.1016/j.jorganchem.2022.122510⟩. ⟨hal-03798833⟩
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