Ligand properties of 1H-diphosphirenes and diphosphirenylium salts towards iron carbonyl fragments

Treatment of η1-[1,3-bis(diisopropylamino)-1H-diphosphirene]tetracarbonyl iron 2 with trifluoromethanesulfonic acid affords the binuclear [3-diisopropylaminodiphosphirenylium salt] iron complex 5, which reacts with diisopropylamine giving the opened binuclear iron complex 3.

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Chimie de coordination

Marie-Hélène Gulli : Connectez-vous pour contacter le contributeur

https://hal.science/hal-03739786

Soumis le : jeudi 28 juillet 2022-11:09:50

Dernière modification le : mardi 22 octobre 2024-13:34:16

Dates et versions

hal-03739786 , version 1 (28-07-2022)

Identifiants

HAL Id : hal-03739786 , version 1
DOI : 10.1039/A904747F

Citer

Didier Bourissou, Yves Canac, Heinz Gornitzka, Antoine Baceiredo, Guy Bertrand. Ligand properties of 1H-diphosphirenes and diphosphirenylium salts towards iron carbonyl fragments. Chemical Communications, 1999, 16, pp.1535-1536. ⟨10.1039/A904747F⟩. ⟨hal-03739786⟩

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