nido-Five-Vertex Clusters: In and Out of Boron Chemistry - Archive ouverte HAL
Article Dans Une Revue Angewandte Chemie International Edition Année : 2003

nido-Five-Vertex Clusters: In and Out of Boron Chemistry

Résumé

During the early days of borane chemistry B5H9 was considered to be the stable pentaborane and although a BH vertex is isolobal with a naked P vertex, it is only recently that the first nido-five-vertex compounds with a naked phosphorus atom at the apical position were discovered. The most recent example is a valence isomer of the hitherto unknown triphosphacyclopentadienyl cation. These results shed light on the relative stability of planar and three-dimensional Cp+ derivatives.

Dates et versions

hal-03739750 , version 1 (28-07-2022)

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Citer

Yves Canac, Guy Bertrand. nido-Five-Vertex Clusters: In and Out of Boron Chemistry. Angewandte Chemie International Edition, 2003, 42 (31), pp.3578-3580. ⟨10.1002/anie.200301648⟩. ⟨hal-03739750⟩

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