Mixing chemo- and biocatalysis for rare monosaccharide production by combining aldolase and N-heterocyclic carbene gold catalysts - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Green Chemistry Année : 2022

Mixing chemo- and biocatalysis for rare monosaccharide production by combining aldolase and N-heterocyclic carbene gold catalysts

Résumé

Chemo- and biocatalysis for multistep reactions were successfully combined to synthesize polyhydroxylated monosaccharides. Gold N-heterocyclic carbene, catalysing green hydration, was coupled to an aldolase to create two stereocenters via C–C bond formation in stereoselective and total atom economy fashions starting from simple and achiral compounds.

Domaines

Chimie
Fichier principal
Vignette du fichier
Green chem.pdf (342.7 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03726536 , version 1 (28-10-2022)

Identifiants

Citer

Cédric Gastaldi, Ghozlene Mekhloufi, Claude Forano, Arnaud Gautier, Christine Guérard-Hélaine. Mixing chemo- and biocatalysis for rare monosaccharide production by combining aldolase and N-heterocyclic carbene gold catalysts. Green Chemistry, 2022, 24 (9), pp.3634-3639. ⟨10.1039/D2GC00667G⟩. ⟨hal-03726536⟩
65 Consultations
36 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More