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Article Dans Une Revue Dalton Transactions Année : 2021

Dihydrogen cleavage by a dimetalloxycarbene-borane frustrated Lewis pair

Résumé

A frustrated Lewis pair of dititanoxycarbene [(Ti(N[Bu-t]Ar)(3))(2)(mu-CO2)] (Ar = 3,5-Me2C6H3) and B(C6F5)(3) cleaved dihydrogen under ambient conditions to give the zwitterionic formate [(Ti(N[Bu-t]Ar)(3))(2)(mu-OCHO-eta O:eta O ')(B(C6F5)(3))] and the hydrido borate [Ti(N[Bu-t]Ar)(3)][HB(C6F5)(3)].
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Dates et versions

hal-03717268 , version 1 (08-07-2022)

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Citer

Albert Paparo, Anh L. P. Nguyen, Jared S. Silvia, Thomas P. Spaniol, Laurent Maron, et al.. Dihydrogen cleavage by a dimetalloxycarbene-borane frustrated Lewis pair. Dalton Transactions, 2021, 50 (31), pp.10692-10695. ⟨10.1039/d1dt02273c⟩. ⟨hal-03717268⟩
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