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Article Dans Une Revue Angewandte Chemie International Edition Année : 2011

Electrochemically Triggered Assembly of Films: A One-Pot Morphogen-Driven Buildup

Résumé

Polymers that “click”: A polymer film is obtained by the CuI-catalyzed Sharpless click reaction between two polymers, bearing either azide or alkyne groups, both present simultaneously in a CuII solution (see picture). The CuI morphogen is generated at an electrode by applying an adequate potential. This concept can be extended to supramolecular films formed by coordination complexes.

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hal-03702226 , version 1 (22-06-2022)

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Gaulthier Rydzek, Loïc Jierry, Audrey Parat, Jean-Sebastien Thomann, Jean Claude Voegel, et al.. Electrochemically Triggered Assembly of Films: A One-Pot Morphogen-Driven Buildup. Angewandte Chemie International Edition, 2011, 50 (19), pp.4374-4377. ⟨10.1002/anie.201007436⟩. ⟨hal-03702226⟩
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