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Journal Articles Organometallics Year : 2022



A representative of the stable alumoles with a chlorine substituent at the aluminum atom was synthesized by the coupling of a cyclobutadiene dianion derivative and aluminum trichloride. The structure of alumole was established by X-ray crystallography, which showed that alumole exists as a monomer. The aluminum atom is tetracoordinated with the fourth coordination site occupied by a thf molecule, which reduces the intrinsically high Lewis acidity of the aluminum center, thus stabilizing the alumole molecule.
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hal-03660785 , version 1 (06-05-2022)



Vladimir Ya. Lee, Haruka Sugasawa, Olga Gapurenko, Ruslan Minyaev, Vladimir Minkin, et al.. 1-Chloroalumole. Organometallics, 2022, 41 (4), pp.467-471. ⟨10.1021/acs.organomet.1c00702⟩. ⟨hal-03660785⟩
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