Mild Palladium‐Catalyzed Cyanation of Unprotected 2‐Iodoglycals in Aqueous Media as Versatile Tool to Access Diverse C2‐Glycoanalogues - Archive ouverte HAL
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2019

Mild Palladium‐Catalyzed Cyanation of Unprotected 2‐Iodoglycals in Aqueous Media as Versatile Tool to Access Diverse C2‐Glycoanalogues

Résumé

Access to unprotected 2-cyano-glycals via a mild palladium-catalyzed cyanation of protecting groups-free 2-iodoglycals in aqueous media has been developed. Diverse glycal substrates including disaccharide-type were successfully obtained in good to excellent yields. These unprotected 2-cyano-glycal scaffolds were successfully derivatized to different C2-glycoanalogues.

Domaines

Chimie organique Catalyse
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Soumis le : mercredi 2 février 2022-16:52:35

Dernière modification le : vendredi 19 avril 2024-12:28:17

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hal-03553259 , version 1 (02-02-2022)

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Citer

Maciej Malinowski, Thanh van Tran, Morgane Robichon, Nadège Lubin‐germain, Angélique Ferry. Mild Palladium‐Catalyzed Cyanation of Unprotected 2‐Iodoglycals in Aqueous Media as Versatile Tool to Access Diverse C2‐Glycoanalogues. Advanced Synthesis and Catalysis, 2019, 362 (5), pp.1184 - 1189. ⟨10.1002/adsc.201901583⟩. ⟨hal-03553259⟩

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