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Article Dans Une Revue Journal of the American Oil Chemists' Society Année : 2011

Phase Equilibrium and Optimization Tools: Application for Enhanced Structured Lipids for Foods

Résumé

Solid-liquid phase equilibrium modeling of triacylglycerols mixtures is essential for lipids design. Considering the α polymorphism and liquid phase as ideal, the Margules 2-suffix excess Gibbs energy model with predictive binary parameter correlations describes the non ideal β and β’ solid polymorphs. Solving by direct optimization of the Gibbs free energy enables to predict from a bulk mixture composition the phases composition at a given temperature and thus the SFC curve, the melting profile and the Differential Scanning Calorimetry (DSC) curve that are related to end-user lipid properties. Phase diagram, SFC and DSC curve experimental data are qualitatively and quantitatively well predicted for the binary mixture 1,3-dipalmitoyl-2-oleoyl-sn-glycerol (POP) and 1,2,3-tripalmitoyl-sn-glycerol (PPP), the ternary mixture 1,3-dimyristoyl-2-palmitoyl-sn-glycerol (MPM), 1,2-distearoyl-3-oleoyl-sn-glycerol (SSO) and 1,2,3-trioleoyl-sn-glycerol (OOO), for palm oil and cocoa butter. Then, addition to palm oil of Medium-Long-Medium type structured lipids is evaluated, using caprylic acid as medium chain and long chain fatty acids (EPA-eicosapentaenoic acid, DHA-docosahexaenoic acid, γ-linolenic-octadecatrienoic acid and AA-arachidonic acid), as sn-2 substitutes. EPA, DHA and AA increase the melting range on both the fusion and crystallization side. γ-linolenic shifts the melting range upwards. This predictive tool is useful for the pre-screening of lipids matching desired properties set a priori.
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Dates et versions

hal-03544042 , version 1 (26-01-2022)

Identifiants

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Moises Teles dos Santos, Galo Carrillo Le Roux, Vincent Gerbaud. Phase Equilibrium and Optimization Tools: Application for Enhanced Structured Lipids for Foods. Journal of the American Oil Chemists' Society, 2011, 88 (2), pp.223-233. ⟨10.1007/s11746-010-1665-z⟩. ⟨hal-03544042⟩
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