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Article Dans Une Revue Chemical Monthly = Monatshefte für Chemie Année : 2015

Phosphite ligands in Ru-based olefin metathesis catalysts

Résumé

In this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong σ-donating NHC ligands and π-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis, and ring-opening metathesis polymerization, as well as DFT calculations describing our mechanistic understanding, are presented.

Domaines

Chimie

Dates et versions

hal-03533954 , version 1 (19-01-2022)

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Citer

Xavier Bantreil, Catherine Cazin. Phosphite ligands in Ru-based olefin metathesis catalysts. Chemical Monthly = Monatshefte für Chemie, 2015, 146 (7), pp.1043-1052. ⟨10.1007/s00706-015-1487-7⟩. ⟨hal-03533954⟩
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