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Article Dans Une Revue Chemistry of Materials Année : 2020

Methylhydrazinium Lead Bromide: Noncentrosymmetric Three-Dimensional Perovskite with Exceptionally Large Framework Distortion and Green Photoluminescence

Résumé

Three-dimensional (3D) lead halide perovskites have emerged as a promising class of coordination polymers for solar cells, photodetectors, and light-emitting devices. These compounds thus far comprise methylammonium, formamidinium, or cesium as cations. In this work, we introduce a new methylhydrazinium 3D perovskite, CH 3 NH 2 NH 2 PbBr 3 , that crystallizes in the polar P2 1 structure at room temperature and undergoes a phase transition to the cubic Pm3̅ m phase at 418 K. This perovskite exhibits strong second-harmonic generation activity, features switchable dielectric behavior, thermochromism, and two-photon energy upconversion under 800 nm excitation.
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Origine : Publication financée par une institution
Licence : CC BY - Paternité

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hal-03527513 , version 1 (15-01-2022)

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Mirosl̷aw Ma̧czka, Maciej Ptak, Anna Ga̧gor, Dagmara Stefańska, Jan Zaręba, et al.. Methylhydrazinium Lead Bromide: Noncentrosymmetric Three-Dimensional Perovskite with Exceptionally Large Framework Distortion and Green Photoluminescence. Chemistry of Materials, 2020, 32 (4), pp.1667-1673. ⟨10.1021/acs.chemmater.9b05273⟩. ⟨hal-03527513⟩
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