Density, Speed of Sound, Compressibility, and Excess Properties of the Carbon Dioxide + n-Heptadecane Binary Mixture from 10 to 70 MPa
Résumé
The density and speed of sound of the carbon dioxide + n-heptadecane binary system were measured at four selected temperatures from 303.15 to 333.15 K and for various pressures ranging from 10 to 70 MPa over the whole composition range. A vibrating U-tube densimeter was employed to measure the density, whereas a pulse-echo technique using a double path length sensor working at 3 MHz was used to obtain the speed of sound data. Isothermal and isentropic compressibilities were determined from both measurements. Finally, the excess volume, excess isothermal compressibility as well as excess speed of sound and excess isentropic compressibility were estimated in the same p, T range and represented as a function of CO2 content. The results, in addition to previous data concerning CO2 + n-heptane and CO2 + n-dodecane binary systems, were analyzed to determine the effect of pressure, temperature, and alkyl chain length on nonideal behaviors of such asymmetric CO2 + n-alkane systems.
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