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Article Dans Une Revue ACS Catalysis Année : 2020

Metal-Catalyzed Asymmetric Hydrogenation of C═N Bonds

Résumé

This review recaps the achievements in the field of metal-catalyzed asymmetric direct hydrogenation of nonactivated and activated imines. A summary of the reported catalytic systems with the corresponding reactivity, selectivity, and limitations are given including a discussion about the effects of some reaction conditions on the enantioselectivity of imine hydrogenation. An analysis of proposed imine hydrogenation mechanisms is discussed.

Domaines

Chimie
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Dates et versions

hal-03453859 , version 1 (28-11-2021)

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Racha Abed Ali Abdine, Gaspard Hedouin, Françoise Colobert, Joanna Wencel-Delord. Metal-Catalyzed Asymmetric Hydrogenation of C═N Bonds. ACS Catalysis, 2020, 11 (1), pp.215-247. ⟨10.1021/acscatal.0c03353⟩. ⟨hal-03453859⟩
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