Article Dans Une Revue Rare Metals Année : 2021

Age stability of La(Fe,Si)13 hydrides with giant magnetocaloric effects

Résumé

The Curie temperatures (T C) of fully hydrogenated La 0.7 Ce 0.3 Fe 13-x-y Mn x Si y compounds are raised to near room temperature. The age stability of La 0.7 Ce 0.3 Fe 11.5-x Mn x Si 1.5 hydrides held at room temperature was investigated. This result indicates that the H content will slowly decrease in the hydrides, leading to a decrease of T C. However, the T C decreases slightly and no age splitting occurs after the hydrides are held at room temperature for two years, indicating the excellent age stability of fully hydrogenated La(Fe,Si) 13-based compounds. Further structural analysis by neutron diffraction shows that the Mn atoms preferentially substitute Fe in the 96i sites. The T C of La 0.7 Ce 0.3 Fe 11.55-y Mn y Si 1.45 hydrides can be adjusted to the desired working temperature by regulating the Mn content based on the linear relationship between T C and Mn content. Moreover, the La 0.7 Ce 0.3 Fe 11.55-y Mn y Si 1.45 hydrides exhibit a giant magnetic entropy change of 15 J/kg K under a low magnetic

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hal-03447163 , version 1 (07-12-2021)

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He Zhou, Yi Long, Salvatore Miraglia, Florence Porcher, Hu Zhang. Age stability of La(Fe,Si)13 hydrides with giant magnetocaloric effects. Rare Metals, 2021, 41, pp.992-1001. ⟨10.1007/s12598-021-01849-3⟩. ⟨hal-03447163⟩
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