Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16− - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Molecules Année : 2020

Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16−

Résumé

Reaction of the trilacunary Wells−Dawson anion {α-P2W15O56}12− with ErIII ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H2O)(CH3COO)(P2W17O61)}2]16− (1). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of 1 were investigated.
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hal-03447052 , version 1 (25-11-2021)

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Masooma Ibrahim, Ananya Baksi, Yan Peng, Firas Khalil Al-Zeidaneen, Israël Mbomekallé, et al.. Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16−. Molecules, 2020, 25 (18), pp.4229. ⟨10.3390/molecules25184229⟩. ⟨hal-03447052⟩
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