A fumarole in a one-pot: synthesis, crystal structure and properties of Zn- and Mg-analogs of itelmenite and a synthetic analog of glikinite - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Physics and Chemistry of Minerals Année : 2021

A fumarole in a one-pot: synthesis, crystal structure and properties of Zn- and Mg-analogs of itelmenite and a synthetic analog of glikinite

Résumé

The structure of the new calcium magnesium iron orthophosphate, Ca2MgFe2(PO4)4 was determined from single crystal X-ray diffraction data. It crystallizes in the orthorhombic system, space group Pbca, with all atoms in general positions among which two sites are disordered. The crystal structure of this phosphate is build up from PO4 tetrahedra linked to FeO6 octahedra and to (Fe/Mg)O5 polyhedra via common vertices. In fact, each of the two mixed sites (Fe/Mg) is surrounded by five oxygen atoms which form either a pyramid with a square base or a bi-pyramid with a triangular base. The interconnection of these polyhedra leads to a three-dimensional structure delimiting cavities where Ca 2+ cations are localized. The powder of this compound was successfully obtained by solid state reaction and its X-ray diffraction diagram was refined by pattern matching method. The magnetic measurements show multiple transition assigned to frustrated triangles locally present in AFM magnetic layered units.
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hal-03438956 , version 1 (24-11-2022)
hal-03438956 , version 2 (24-11-2022)

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Diana O Nekrasova, Oleg I Siidra, Anatoly N. Zaitsev, Valery L. Ugolkov, Marie Colmont, et al.. A fumarole in a one-pot: synthesis, crystal structure and properties of Zn- and Mg-analogs of itelmenite and a synthetic analog of glikinite. Physics and Chemistry of Minerals, 2021, 48 (1), pp.6. ⟨10.1007/s00269-020-01132-4⟩. ⟨hal-03438956v1⟩
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