Electrosynthesis of a functional conducting polymer incorporating ferrocene unit from an EDOT-based bithiophenic precursor - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Electroanalytical Chemistry Année : 2007

Electrosynthesis of a functional conducting polymer incorporating ferrocene unit from an EDOT-based bithiophenic precursor

Aude-Emmanuelle Navarro
  • Fonction : Auteur
Fabrice Moggia
  • Fonction : Auteur
Bruno Jousselme
Philippe Blanchard
Jean Roncali
  • Fonction : Auteur

Résumé

A precursor of electrogenerated functional polythiophene combining an EDOT moiety with a thiophene ring on which a ferrocene group is attached at the internal β-position via a sulphide linkage (1) has been synthesized and characterized. The electrochemical polymerization of this precursor has been investigated in potentiodynamic and potentiostatic conditions. The analysis of the electrochemical behavior of the films growth under various conditions shows that potentiostatic polymerization of 1 in nitrobenzene leads to a polymer which exhibit the electroactivity of the polythiophene backbone and that of the attached ferrocene moiety.

Domaines

Chimie

Dates et versions

hal-03409104 , version 1 (29-10-2021)

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Citer

Hugues Brisset, Aude-Emmanuelle Navarro, Fabrice Moggia, Bruno Jousselme, Philippe Blanchard, et al.. Electrosynthesis of a functional conducting polymer incorporating ferrocene unit from an EDOT-based bithiophenic precursor. Journal of Electroanalytical Chemistry, 2007, 603 (1), pp.149-154. ⟨10.1016/j.jelechem.2007.01.017⟩. ⟨hal-03409104⟩

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