DFT Analysis into the Calcium(II)-Catalyzed Coupling of Alcohols With Vinylboronic acids: Cooperativity of Two Different Lewis Acids and Counterion Effects
Résumé
The mechanism of the calcium-catalyzed coupling of alcohols with vinylboronic acids has been analyzed by means of DFT computations. This study reveals that the calcium and the boron Lewis acids associate to form a superelectrophile able to promote a pericyclic group
Domaines
Chimie
Origine : Fichiers produits par l'(les) auteur(s)