The kinetics of X + H2 reactions (X = C(1D), N(2D), O(1D), S(1D)) at low temperature: recent combined experimental and theoretical investigations - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue International Reviews in Physical Chemistry Année : 2021

The kinetics of X + H2 reactions (X = C(1D), N(2D), O(1D), S(1D)) at low temperature: recent combined experimental and theoretical investigations

Résumé

In recent years, combined experimental and theoretical e orts have brought valuable information on the kinetics of reactive collisions between molecular hydrogen and an electronically excited atom X (where X = C(1D), N(2D), O(1D) or S(1D)). These four reactions have been comparatively studied together in numerous occasions in the past due to the similar importance of complex-forming mechanisms found in their overall dynamics. In this work, we compile the most updated information on these investigations making a special emphasis from the theoretical side on statistically based techniques, in an attempt to test the possible insertion nature of the overall dynamics. Besides a description of the experimental details of the kinetics investigation, a comparison of the measured rate constants over a temperature range between 50 K and 300 K with the most recent theoretical calculations is presented.
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hal-03374348 , version 1 (12-10-2021)

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Kevin Hickson, Pascal Larrégaray, Laurent Bonnet, Tomás González-Lezana. The kinetics of X + H2 reactions (X = C(1D), N(2D), O(1D), S(1D)) at low temperature: recent combined experimental and theoretical investigations. International Reviews in Physical Chemistry, 2021, 40 (4), pp.457-493. ⟨10.1080/0144235X.2021.1976927⟩. ⟨hal-03374348⟩
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