Dihydrogen is one of the sustainable energy vectors envisioned for the future. However, the rapidly reversible and secure storage of large quantities of hydrogen is still a technological and scientific challenge. In this context, this review proposes a recent state-of-the-art on H 2 production capacities from the dehydrogenation reaction of ammonia borane (and selected related amine-boranes) as a safer solid-source of H 2 by hydrolysis (or solvolysis), according to the different developed nanoparticle-based catalysts. The review groups the results according to the transition metals constituting the catalyst according a special view to current cost/availability consideration. This includes the noble metals Rh, Pd, Pt, Ru, Ag, as well as transition metals such as Co, Ni, Cu, and Fe. For each element, the monometallic and polymetallic structures, isolated or supported, are presented and the performances described in terms of TOF and recyclability. The structure-property links are highlighted whenever possible. It appears from all these works that the mastery of the preparation of catalysts remains a crucial point; not only in terms of process but also in terms of mastery of the electronic structures of the elaborated nanomaterials. A particular effort of the scientific community remains to be made in this multidisciplinary field with major societal stakes.