Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue ChemElectroChem Année : 2021

Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction

Résumé

The mass scale catalytic transformation of carbon dioxide (CO2) into reduced forms of carbon is an imperative to address the ever-increasing anthropogenic emission. Understanding the mechanistic routes leading to the multi-electron-proton conversion of CO2 provides handles for chemists to overcome the kinetically and thermodynamically hard challenges and further optimize these processes. Through extensive electrochemical investigations, Prof. J-M. Savéant and coworkers have made accessible to chemists invaluable electro-analytical tools to address and position the electrocatalytic performance of molecular catalysts grounded on a theoretical basis. Furthermore, he has bequeathed lessons to future generations on ways to improve the catalytic activity and on the electrocatalytic zone we must target. As a tribute to his accomplishments, we recall here a few aspects on the tuning of iron porphyrin catalysts by playing on electronic effects, proton delivery, hydrogen bonding and electrostatic interactions and its implications to other catalytic systems.
Fichier principal
Vignette du fichier
ChemElectChem Minireview_V2_draft3.pdf (1.21 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03279622 , version 1 (06-07-2021)

Identifiants

Citer

Philipp Gotico, Winfried A Leibl, Zakaria Halime, Ally Aukauloo. Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction. ChemElectroChem, In press, ⟨10.1002/celc.202100476⟩. ⟨hal-03279622⟩
77 Consultations
94 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More