Dendrimers Functionalized with Palladium Complexes of N-, N,N-, and N,N,N-Ligands - Archive ouverte HAL Access content directly
Journal Articles Molecules Year : 2021

Dendrimers Functionalized with Palladium Complexes of N-, N,N-, and N,N,N-Ligands

Abstract

Pyridine, pyridine imine, and bipyridine imine ligands functionalized by a phenol have been synthesized and characterized, in many cases by X-ray diffraction. Several of these N-, N,N-, and N,N,N,-ligands have been grafted onto the surface of phosphorhydrazone dendrimers, from generation 1 to generation 3. The complexation ability of these monomers and dendrimers towards palladium(II) has been assayed. The corresponding complexes have been either isolated or prepared in situ. In both cases, the monomeric and dendritic complexes have been tested as catalysts in Heck couplings and in Sonogashira couplings. In some cases, a positive dendritic effect has been observed, that is, an increase of the catalytic efficiency proportional to the dendrimer generation.
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hal-03275902 , version 1 (01-07-2021)

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Quentin Vanbellingen, Paul Servin, Anaïs Coinaud, Sonia Mallet-Ladeira, Regis Laurent, et al.. Dendrimers Functionalized with Palladium Complexes of N-, N,N-, and N,N,N-Ligands. Molecules, 2021, 26 (8), pp.2333. ⟨10.3390/molecules26082333⟩. ⟨hal-03275902⟩
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